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Orthopaedic Proceedings
Vol. 99-B, Issue SUPP_3 | Pages 9 - 9
1 Feb 2017
Aldinger P Pawar V
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INTRODUCTION

Due to increasing interest into taper corrosion observed primarily in hip arthroplasty devices with modular tapers, efforts towards characterizing the corrosion byproducts are prevalent in the literature [1–4]. As a result of this motivation, several studies postulate cellular induced corrosion due to the presence of remarkable features in the regions near taper junction regions and articulating surfaces [3–5]. Observations made on explanted devices from a retrieval database as well as laboratory tests have led to the alternative proposal of electrocautery-electrosurgery damage as the cause of these features. These surgical instruments are commonly used for hemostasis or different degrees of tissue dissection.

METHODS

Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to evaluate the features observed on retrieved devices. Retrieved devices consisted of OXINIUM and cobalt-chromium-molybdenum (CoCrMo) femoral implants, a Titanium-alloy hip stem, and a CoCrMo metal-on-metal femoral head. Electrocautery-electrosurgery damage was created using a SurgiStat II (Valleylab, Colorado) onto various components (CoCrMo, OXINIUM femoral heads as well as Ti-6Al-4V and CoCrMo alloy test stem constructs). Test components were evaluated using the same methods as the retrieved devices.


Orthopaedic Proceedings
Vol. 94-B, Issue SUPP_XXV | Pages 153 - 153
1 Jun 2012
Parikh A Hill P Pawar V Morrison M
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Introduction

Large diameter femoral heads offer increased range of motion and reduced risk of dislocation. However, their use in total hip arthroplasty has historically been limited by their correlation with increased polyethylene wear. The improved wear resistance of highly crosslinked UHWMPE has led a number of clinicians to transition from implanting traditionally popular sizes (28mm and 32 mm) to implanting 36 mm heads. Desire to further increase stability and range of motion has spurred interest in even larger sizes (> 36 mm). While the long-term clinical ramifications are unknown, in-vivo measurements of highly crosslinked UHMWPE liners indicate increases in head diameter are associated with increased volumetric wear [1]. The goal of this study was to determine if this increase in wear could be negated by using femoral heads with a ceramic surface, such as oxidized Zr-2.5Nb (OxZr), rather than CoCrMo (CoCr). Specifically, wear of 10 Mrad crosslinked UHMWPE (XLPE) against 36 mm CoCr and 44 mm OxZr heads was compared.

Materials and Methods

Ram-extruded GUR 1050 UHMWPE was crosslinked by gamma irradiation to 10 Mrad, remelted, and machined into acetabular liners. Liners were sterilized using vaporized hydrogen peroxide and tested against either 36 mm CoCr or 44 mm OxZr (OXINIUM(tm)) heads (n=3). All implants were manufactured by Smith & Nephew (Memphis, TN).

Testing was conducted on a hip simulator (AMTI, Watertown, MA) as previously described [2]. The 4000N peak load (4 time body weight for a 102 kg/225 lb patient) and 1.15 Hz frequency used are based upon data obtained from an instrumented implant during fast walking/jogging and have previously been shown to generate measurable XLPE wear [2,3]. Lubricant was a serum (Alpha Calf Fraction, HyClone Laboratories, Logan, UT) solution that was replaced once per week [2]. Liners were weighed at least once every million cycles (Mcycle) over the duration of testing (∼ 5 Mcycle). Loaded soak controls were used to correct for fluid absorption. Single factor ANOVA was used to compare groups (a = 0.05).


Orthopaedic Proceedings
Vol. 90-B, Issue SUPP_I | Pages 176 - 176
1 Mar 2008
Marek M Pawar V Tsai S Thomas R Sprague J Hunter G Salehi A
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Due to their superior wear characteristics, oxidized Zr-2.5Nb heads are used with hip stems made of conventional orthopaedic alloys. Galvanic interactions between Zr-2.5Nb (Zr) and Ti-6Al-4V (Ti), cobalt-chromium (CoCr), and 316L stainless steel (SS) alloys were evaluated.

Galvanic current density was measured for Zr/Ti,Zr/CoCr, Zr/SS, CoCr/Ti, and CoCr/SS couples under static conditions in aneutral Ringer’s solution and in an acidic (1.7 pH) solution. To simulate fretting, one or both coupled alloys in the neutral solution subsequently were abraded by a bone cement pin (82 MPa Hertzian stress). An extended(7-day) static test in the acidic solution was performed for Zr/SS and CoCr/Ti to simulate crevice conditions. The dissolved metal ion concentration was determined using direct coupled plasma emission spectrometry.

Mean initial current densities of the Zr/SS, SS/CoCr,Zr/CoCr, CoCr/Ti, and Zr/Ti couples were 3.0, 0.36, 0.16, 0.05, and 0.04μA/cm2, respectively, in the neutral solution, and 0.57, −0.29, 0.04, 0.02, and 0.03 μA/cm2, respectively, in the acidic solution (positive when first alloy was anode). Within 30 minutes, all values decreased below 0.02μA/cm2. The current densities increased by orders of magnitude under fretting conditions. When both alloys were abraded, the highest values were minus;677 and 464 μA/cm2 for CoCr/Ti and Zr/SS, respectively. In the extended static test of Zr/SS, the mean total metal ion concentration decreased from 8.15 mg/L when the alloys were uncoupled to 4.50 mg/L(p=0.007) when they were coupled. For CoCr/Ti, the change from 1.28 to 1.72mg/L when the alloys were coupled was not statistically significant(p=0.22).

With its strong tendency to passivate, the Zr alloy produced galvanic interactions within the range observed with conventional alloy couples. Its anodic characteristic helped protect SS in a galvanic couple.